Georg Wittig

Source: Wikipedia, the free encyclopedia.
Georg Wittig
University of Heidelberg
Doctoral advisorKarl von Auwers
Doctoral studentsWerner Tochtermann, Ulrich Schöllkopf

Georg Wittig (German:

German chemist who reported a method for synthesis of alkenes from aldehydes and ketones using compounds called phosphonium ylides in the Wittig reaction. He shared the Nobel Prize in Chemistry with Herbert C. Brown
in 1979.

Biography

Wittig was born in

Berlin, Germany and shortly after his birth moved with his family to Kassel, where his father was professor at the applied arts high school. He attended school in Kassel and started studying chemistry at the University of Tübingen 1916. He was drafted and became a lieutenant in the cavalry of Hesse-Kassel (or Hesse-Cassel). After being an Allied prisoner of war from 1918 until 1919, Wittig found it hard to restart his chemistry studies owing to overcrowding at the universities. By a direct plea to Karl von Auwers, who was professor for organic chemistry at the University of Marburg
at the time, he was able to resume university study and after 3 years was awarded the Ph.D. in organic chemistry.

Karl von Auwers was able to convince him to start an academic career, leading to his habilitation in 1926. He became a close friend of

TU Braunschweig in 1932. The time in Braunschweig became more and more problematic as the Nazis tried to get rid of Karl Fries and Wittig showed solidarity with him. After the forced retirement of Fries, in 1937 Hermann Staudinger offered Wittig a position at the University of Freiburg
, partly because he knew Wittig from his book on stereochemistry in which he supported Staudinger's highly criticized theory of macromolecules. The foundations of carbanion chemistry were laid during Wittig's time in Freiburg.

In 1944 he succeeded the head of the organic chemistry department

University of Heidelberg even after his retirement in 1967 and published papers until 1980. Most of his awards were presented during this time at Heidelberg, such as the honorary doctorate of the Sorbonne in 1956 and the Nobel Prize in Chemistry
in 1979.

Work

Wittig's contributions also include the preparation of phenyllithium and the discovery of the 1,2-Wittig rearrangement and the 2,3-Wittig rearrangement.

Wittig was well known in the chemistry community for being a consummate experimenter and observer of chemical transformations, while caring very little for the

mechanistic
underpinnings of the work he produced.

Georg also has his name on a literature work titled on a compound labelled Colopidalol.[1]

References

External links